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Hydroxyl-Directed Intermolecular Ketone - Olefin Couplings
Summary
Type: TLCApplication #: 402490
Catalog#: 1615126 - Silica G TLC Plates, w/UV254, glass backed, 250um, 20x20cm 25/pk
Detection: UV, 254 nm and development using phosphomolybdic acid solution (phosphomolybdic acid (25 g), Ce(SO4)2 • 4 H2O (10 g), H2SO4 (60 ml) H2O (940 ml))
Conditions: Eluents: ethyl acetate / hexane
Authors: Matsuda Fuyuhiko Kawatsura Motoi Hosaka Ken-ichi Shirahama Haruhisa
Source: Chem Eur J 1999 5 3252-3259
Details
Legend: Compound RF-value Ratio of eluents (4R*,5R*)-4,5-Dihydroxy-4-methyl-7-phenylheptanenitrile (syn-diol) 0.23 40:60 v/v (4R*,5R*,1'R*)-Tetrahydro-5-(1-hydroxy-3-phenylpropyl)-4,5-dimethyl-2-furanon